Indium tribromide: an efficient catalyst for the silylation of hydroxy groups by the activation of hexamethyldisilazane

Yadav, J. S. ; Reddy, B. V. S. ; Basak, A. K. ; Baishya, G. ; Venkat Narsaiah, A. (2006) Indium tribromide: an efficient catalyst for the silylation of hydroxy groups by the activation of hexamethyldisilazane Synthesis, 2006 (22). pp. 3831-3834. ISSN 0039-7881

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2006-950322

Abstract

A variety of substrates containing hydroxy groups have been protected as their corresponding trimethylsilyl ethers using 1,1,1,3,3,3-hexamethyldisilazane in the presence of indium tribromide. The catalyst indium tribromide activates the 1,1,1,3,3,3-hexa-methyldisilazane and accelerates the reaction under mild reaction conditions at room temperature.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Indium Tribromide; 1,1,1,3,3,3-hexamethyldisilazane; Protection; Hydroxy Group; Silylation
ID Code:63220
Deposited On:28 Sep 2011 03:25
Last Modified:28 Sep 2011 03:25

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