A formal stereoselective synthesis of (−)-maurenone

Yadav, J. S. ; Ravindar, K. ; Reddy, B. V. S. (2007) A formal stereoselective synthesis of (−)-maurenone Synlett, 2007 (12). pp. 1957-1959. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2007-984497

Abstract

An efficient formal synthesis of marine polypropionate (−)-maurenone is described. Highlights of the strategy include the utilization of a desymmetrization technique and the activation of the epoxide oxygen with a silyl triflate followed by intramolecular -hydride transfer - a novel transformation.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Desymmetrization; Sharpless Asymmetric Epoxidation; Polyketide
ID Code:63200
Deposited On:28 Sep 2011 03:28
Last Modified:28 Sep 2011 03:28

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