Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Madhusudhan Reddy, Ganapuram ; Narender, Ravirala (2009) Iodine-catalyzed three-component reaction: A rapid synthesis of α-alkoxy azides and homoallyl ethers Synthesis, 6 . pp. 963-968. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-0028-1087802
Abstract
Iodine is found to be an efficient catalyst for the three-component coupling of aldehydes, alcohols, and TMSN3 under mild and neutral conditions to provide α-alkoxy azides in good yields and with high selectivity. Allyltrimethylsilane also reacts rapidly with aldehydes in the presence of alcohols to produce homoallyl ethers under similar conditions. The use of iodine makes this procedure simple, convenient and cost-effective.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Three-component Reaction; Molecular Iodine; α-alkoxy Azides; Homoallylic Ethers |
| ID Code: | 63183 |
| Deposited On: | 28 Sep 2011 03:40 |
| Last Modified: | 28 Sep 2011 03:40 |
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