Total synthesis of pteridic acid A

Yadav, J. S. ; Rajender, V. ; Gangadhara Rao, Y. (2009) Total synthesis of pteridic acid A Organic Letters, 12 (2). pp. 348-350. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol9026842

Related URL: http://dx.doi.org/10.1021/ol9026842

Abstract

A convergent approach to the total synthesis of pteridic acid A, having potent plant growth regulator activity, is described. Key steps include the desymmetrization of bicyclic olefin with Brown's chiral hydroboration, acid-mediated spiroketalization, and zirconium-catalyzed ethylmagnesation protocol to install the ethyl stereocenter at C14.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:63170
Deposited On:28 Sep 2011 03:42
Last Modified:28 Sep 2011 03:42

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