Stereoselective synthesis of (−)-PF1163A via Prins cyclization

Yadav, Jhillu S. ; Venkatesh, M. ; Thrimurtulu, N. ; Prasad, Attaluri R. (2010) Stereoselective synthesis of (−)-PF1163A via Prins cyclization Synlett, 2010 (8). pp. 1255-1259. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-0029-1219839

Abstract

A highly stereoselective and convergent total synthesis of PF1163 A is described while proving the versatility of Prins cyclization in natural product synthesis. The Prins cyclization, Yamaguchi esterification, and ring-closing metathesis reactions are the key steps utilized in the synthesis of macrolactone.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:(−)-PF1163A; 13-membered Macrolactone; Prins Cyclization; Ring-closing Metathesis
ID Code:63154
Deposited On:28 Sep 2011 03:46
Last Modified:28 Sep 2011 03:46

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