Yadav, Jhillu Singh ; Biswas, Swapan Kumar ; Sengupta, Sandip (2010) Progress towards the total synthesis of 2,3-dihydroxytrinervitanes Tetrahedron Letters, 51 (31). pp. 4014-4016. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.03.065
Abstract
Intramolecular Diels-Alder approach to construct the fused AB ring of trinervitane has been demonstrated efficiently. The key intermediate for the Diels-Alder cyclization has been achieved following highly stereoselective Julia-Kocienski olefination, Sharpless epoxidation and Evan's asymmetric alkylation as the key reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Trinervitanes; Intramolecular Diels-Alder Reaction; Julia-Kocienski Olefination; Evan's Asymmetric Alkylation |
| ID Code: | 63145 |
| Deposited On: | 28 Sep 2011 03:49 |
| Last Modified: | 28 Sep 2011 03:49 |
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