A mild and selective cleavage of tritylethers by cerium(III) chloride

Yadav, J. S. ; Subba Reddy, B. V. (2000) A mild and selective cleavage of tritylethers by cerium(III) chloride Synlett, 2000 (9). pp. 1275-1276. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2000-7141

Abstract

Trityl ethers are selectively cleaved by cerium(III) chloride in high yields in refluxing acetonitrile under neutral reaction conditions. The method is compatible with other acid sensitive functional groups like acetonide, acetate, benzoate, BOC, Cbz, benzyl, TBDPS, PMB, allyl, methyl and tetrahydropyranyl ethers present in the molecule.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Cerium(III) Chloride; Trityl Ethers; Alcohols
ID Code:63129
Deposited On:28 Sep 2011 03:18
Last Modified:28 Sep 2011 03:18

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