Substrate-controlled stereoselective synthesis of ophiocerin C

Yadav, Jhillu S. ; Rami Reddy, N. ; Bala Murali Krishna, B. ; Vijaya Vardhan, Ch. ; Subba Reddy, Basi V. (2010) Substrate-controlled stereoselective synthesis of ophiocerin C Synthesis, 2010 (10). pp. 1621-1624. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-0029-1218708

Abstract

A novel stereoselective total synthesis of ophiocerin C was accomplished starting from L-(+)-tartaric acid. The C3,C4 vic-diol moiety was obtained from tartaric acid, and the stereogenic centre at C6 was created by substrate-controlled epoxidation and subsequent regioselective cleavage of the epoxide ring.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Wittig Reactions; Tartaric Acid; Epoxidations; Ring Opening; Ophiocerin C; Stereoselective Synthesis
ID Code:63121
Deposited On:28 Sep 2011 03:46
Last Modified:28 Sep 2011 03:46

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