Yadav, Jhillu S. ; Mallikarjuna Reddy, N. ; Adi Narayana Reddy, P. ; Ather, Hissana ; Prasad, Attaluri R. (2010) Stereoselective total synthesis of (-)-colletol by Prins cyclisation Synthesis, 2010 (9). pp. 1473-1478. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0029-1218679
Abstract
A simple and efficient asymmetric total synthesis of the bis-macrolactone (-)-colletol was accomplished, proving the versatility of the Prins cyclisation in natural product synthesis. The synthesis mainly relies upon reductive opening of a pyran ring, Mitsunobu inversion, the Wittig reaction, and Yamaguchi macrolactonisation as the key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Natural Products; Prins Cyclization; Mitsunobu Reaction; Macrolactonization; Lactones |
| ID Code: | 63115 |
| Deposited On: | 28 Sep 2011 03:46 |
| Last Modified: | 28 Sep 2011 03:46 |
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