Yadav, J. S. ; Hari Krishna, V. ; Srilatha, A. ; Somaiah, R. ; Subba Reddy, B. V. (2010) Stereoselective total synthesis of leiocarpin C and (+)-goniodiol Synthesis, 2010 (17). pp. 3004-3012. ISSN 0039-7881
Full text not available from this repository.
Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0030-1257858
Abstract
Total syntheses of styryl lactones, leiocarpin C and (+)-goniodiol have been accomplished in a highly stereoselective manner. The key steps involved in these syntheses are the Chan alkyne reduction, Sharpless asymmetric dihydroxylation, Horner-Wadsworth-Emmons olefination, aryl Grignard reaction, hydroboration, stereoselective alkoxy-directed keto-reduction, stereoselective 1,3-anti-allylation, esterification via ozonolysis, and intramolecular lactonization.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Styryl Lactones; Dihydroxylation; Olefination; Hydroboration; 1,3-anti-allylation; Ozonolysis |
| ID Code: | 63104 |
| Deposited On: | 28 Sep 2011 03:45 |
| Last Modified: | 28 Sep 2011 03:45 |
Repository Staff Only: item control page
