Yadav, J. S. ; Thrimurtulu, N. ; Venkatesh, M. ; Prasad, A. R. (2010) The stereoselective total synthesis of aculeatin A and B via Prins cyclization Synthesis, 2010 (3). pp. 431-436. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0029-1217144
Abstract
The total synthesis of aculeatins A and B is described proving the versatility of Prins cyclization in natural product synthesis. The approach is convergent and highly stereoselective. Morpholine amide coupling with an alkyne and PIFA-mediated oxidative spirocyclization were utilized as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Aculeatins; Prins Cyclization; Morpholine Amide; PIFA-mediated Oxidative Spirocyclization |
| ID Code: | 63074 |
| Deposited On: | 28 Sep 2011 03:46 |
| Last Modified: | 28 Sep 2011 03:46 |
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