Yadav, J. S. ; Murali Krishna Reddy, P. ; Gupta, Manoj K. ; Janardhana Chary, Ch. (2007) Stereoselective total synthesis of tarchonanthuslactone and formal synthesis of (−)-colletol Synthesis, 2007 (23). pp. 3639-3646. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-2007-990850
Abstract
A simple and efficient stereoselective total synthesis of tarchonanthuslactone and formal synthesis of (−)-colletol is described using as the key steps Jacobsen's kinetic resolution and a Sharpless asymmetric epoxidation. The synthesis of tarchonanthuslactone and the seco acid proceeded in 14% and 13% overall yield, respectively, starting from chiral (R)-propylene oxide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Hydrolytic Kinetic Resolution; PMB Acetal Formation; Sharpless Asymmetric Epoxidation; Lactonization; One-pot Oxidation; Alkenation; Esterification |
| ID Code: | 63072 |
| Deposited On: | 28 Sep 2011 03:28 |
| Last Modified: | 28 Sep 2011 03:28 |
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