Phase selection in electrohydrodynamic atomization of alumina

Levi, C. G. ; Jayaram, V. ; Valencia, J. J. ; Mehrabian, R. (1988) Phase selection in electrohydrodynamic atomization of alumina Journal of Materials Research, 3 (5). pp. 969-983. ISSN 0884-2914

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Electrohydrodynamic atomization'has been adapted to produce Al2O3 powders ranging in size from 10 nm to 300 μm. Microstructural characterization using x-ray diffraction, scanning, and transmission electron microscopy reveals changes in phase selection as a function of particle size, hence supercooling. Amorphous powders are common below 100 nm in diameter. Cubic spinel γ is found in single phase form between 100 nm and 2μm, and partially transformed to δ between 2 and 20 μm. There is also evidence of σ and θ or a precursor of θ forming directly from the liquid above 5 μm. The stable corundum structure is consistently found above 20 μm but exhibits three different morphologies: faceted, dendritic, and cellular. Phase selection is examined on the basis of fundamental thermodynamic and kinetic considerations and results from computer models predicting the thermal history of the powders. It is concluded that metastable phases require the elimination of catalytic sites for the nucleation of a and are thus more likely to form in the smaller powders. Furthermore, submicron powders achieve sufficiently high cooling rates to preserve the metastable phases formed (γ), but those higher than ~1 μm experience a thermal excursion long enough to transform γ to more stable forms of Al2O3.

Item Type:Article
Source:Copyright of this article belongs to Cambridge University Press.
ID Code:63033
Deposited On:24 Sep 2011 14:59
Last Modified:24 Sep 2011 14:59

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