Chandrasekhar, S. ; Narsihmulu, Ch. ; Shameem Sultana, S. ; Srinivasa Reddy, M. (2004) The first stereoselective total synthesis of (6S)-5,6-dihydro-6-[(2R)-2-hydroxy-6-phenylhexyl]-2H-pyran-2-one Tetrahedron Letters, 45 (50). pp. 9299-9301. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.10.059
Abstract
Iterative asymmetric allylations and ring-closing metathesis have been effectively performed for the first stereoselective total synthesis of (6S)-5,6-dihydro-6-[(2R)-2-hydroxy-6-phenylhexyl]-2H-pyran-2-one, a novel α,β-unsaturated-δ-lactone having antifungal activity, isolated from Ravensara crassifolia.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Maruoka Asymmetric Allylation; Keck Asymmetric Allylation; Ring-Closing Metathesis |
| ID Code: | 62882 |
| Deposited On: | 24 Sep 2011 05:17 |
| Last Modified: | 24 Sep 2011 05:17 |
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