Scandium triflate catalyzed allylation of acetals and gem-diacetates: a facile synthesis of homoallyl ethers and acetates

Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Srihari, P. (2001) Scandium triflate catalyzed allylation of acetals and gem-diacetates: a facile synthesis of homoallyl ethers and acetates Synlett, 2001 (5). 0673-0675. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2001-13379

Abstract

Scandium triflate catalyzes efficiently the allylation reactions of acetals and gem-diacetates with allyltrimethylsilane at ambient temperature to afford the corresponding homoallyl ethers and acetates in high yields. Also it is found to be effective for the direct formation of homoallyl ethers from aldehydes and allylsilane in presence of trimethylorthoformate.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Scandium Triflate; Allyltrimethylsilane; Homoallyl Ethers; Homoallyl Acetates
ID Code:62859
Deposited On:24 Sep 2011 04:37
Last Modified:24 Sep 2011 04:37

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