Bismuth (III) chloride: an efficient catalyst for the one-pot stereoselective synthesis of octahydroacridines

Sabitha, Gowravaram ; Venkata Reddy, Erigala ; Yadav, Jhillu S. (2002) Bismuth (III) chloride: an efficient catalyst for the one-pot stereoselective synthesis of octahydroacridines Synthesis, 2002 (3). 0409-0412. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2002-20045

Abstract

A one-pot procedure for the stereocontrolled preparation of octahydroacridine derivatives is reported, which involves the intramolecular hetero-Diels-Alder reaction of N-arylimines produced in situ from citronellal and aromatic amines. The temperature of the reaction medium plays a key role in determination of the trans/cis ratio.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Bismuth(iii) Chloride; Diastereoselective; One-pot Procedure; Hetero-Diels-Alder Reaction
ID Code:62842
Deposited On:24 Sep 2011 04:39
Last Modified:24 Sep 2011 04:39

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