Iodine as a mild, efficient, and cost-effective catalyst for the synthesis of thiiranes from oxiranes

Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Sengupta, Sandip ; Gupta, Manoj K. ; Baishya, Gakul ; Harshavardhana, Sukkala J. ; Dash, Uttam (2008) Iodine as a mild, efficient, and cost-effective catalyst for the synthesis of thiiranes from oxiranes Chemical Monthly, 139 (11). pp. 1363-1367. ISSN 0026-9247

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Official URL: http://www.springerlink.com/content/42vh626212n726...

Related URL: http://dx.doi.org/10.1007/s00706-008-0925-1

Abstract

We developed an efficient protocol for the synthesis of thiiranes from oxiranes using a catalytic amount of molecular iodine. The notable features of this procedure are mild reaction conditions, high conversions, short reaction times, economic viability of the reagents, compatibility with various functionalities, and simple experimental/product isolation procedures which make it a useful and attractive process for the synthesis of a range of thiiranes.

Item Type:Article
Source:Copyright of this article belongs to Springer.
Keywords:Oxiranes; Thiiranes; Iodine; Ammonium Thiocyanate
ID Code:62797
Deposited On:24 Sep 2011 04:56
Last Modified:24 Sep 2011 04:56

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