InCl3-catalyzed stereoselective synthesis of 1,5-benzodiazepines

Yadav, J. S. ; Reddy, B. V. S. ; Satheesh, G. ; Srinivasulu, G. ; Kunwar, A. C. (2005) InCl3-catalyzed stereoselective synthesis of 1,5-benzodiazepines ARKIVOC: Online Journal of Organic Chemistry, 2005 (3). pp. 221-227. ISSN 1424-6376

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Official URL: http://www.arkat-usa.org/get-file/19962/

Abstract

o-Phenylenediamines (OPDA) undergo smooth condensation with 4,6-di-O-benzyl- or 4,6-di-O-acetyl- or 4,6-di-O-ethyl-2,3-dideoxy-aldehydo-D-erythro-trans-hex-2-enose derived from D-glucal in the presence of 2 mol% of InCl3 under mild conditions to afford a new class of 1,5- benzodiazepines in good yields.

Item Type:Article
Source:Copyright of this article belongs to Arkat-USA, Inc.
Keywords:Vic-diamines; α,β-unsaturated-δ-hydroxyaldehyde; Diazepines
ID Code:62787
Deposited On:24 Sep 2011 04:50
Last Modified:18 May 2016 11:54

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