Yadav, J. S. ; Pratap, T. V. ; Rajender, V. (2007) Stereoselective formal total synthesis of (+)-methynolide Journal of Organic Chemistry, 72 (15). pp. 5882-5885. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0704762
Related URL: http://dx.doi.org/10.1021/jo0704762
Abstract
A highly stereoselective and convergent formal total synthesis of (+)-methynolide is described. The salient features of this synthesis have been the construction of the C1-C7 and C8-C11fragments via a desymmetrization approach, Sharpless asymmetric epoxidation of an allyl alcohol, respectively, and linkage of both the fragments by Nozaki-Hiyama-Kishi reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 62770 |
| Deposited On: | 24 Sep 2011 04:54 |
| Last Modified: | 24 Sep 2011 04:54 |
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