InCl3-catalyzed highly regioselective ring opening of epoxides with thiols

Yadav, J. S. ; Reddy, B. V. S. ; Baishya, Gakul (2002) InCl3-catalyzed highly regioselective ring opening of epoxides with thiols Chemistry Letters, 31 (9). pp. 906-907. ISSN 0366-7022

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Official URL: http://www.jstage.jst.go.jp/article/cl/31/9/31_906...

Related URL: http://dx.doi.org/10.1246/cl.2002.906

Abstract

Epoxides react smoothly with thiols in the presence of 10 mol% InCl3 under very mild conditions to afford the corresponding β-hydroxy sulfides in high yields with high regioselectivity. Similar yields and selectivity are also obtained with catalytic amount of indium triflate under these reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to Chemical Society of Japan.
ID Code:62755
Deposited On:24 Sep 2011 04:39
Last Modified:24 Sep 2011 04:39

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