Zirconium(IV) chloride-mediated chemoselective conjugate addition of aliphatic amines to α,β-ethylenic compounds

Meshram, H. M. ; Lakshindra, C. ; Reddy, P. N. ; Sadashiv, K. ; Yadav, J. S. (2006) Zirconium(IV) chloride-mediated chemoselective conjugate addition of aliphatic amines to α,β-ethylenic compounds Synthetic Communications, 36 (6). pp. 795-801. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397910500451423

Abstract

Zirconium chloride efficiently catalyzes the conjugate addition of a variety of aliphatic amines to α,β-unsaturated ester, nitriles, and ketones to give the corresponding β-amino derivatives in excellent yields under mild reaction conditions. Aromatic amines do not participate in this transformation.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
Keywords:Amines; Michael Addition; α,β-unsaturated Compounds; Zirconium(IV) Chloride
ID Code:62697
Deposited On:24 Sep 2011 04:51
Last Modified:24 Sep 2011 04:51

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