Reactivity of the dirhenium(III) carboxylate complexes Re₂(O₂CCH₃)₂X₄(H₂O)₂ (X = Cl or Br) toward monodentate phosphines. A novel disproportionation reaction leading to dirhenium(IV,II) alkoxide complexes of the type (RO)2X2ReReX2(PPh3)2 (X = Cl or Br; R = Me, Et, or Pr)

Chakravarty, Akhil R. ; Albert Cotton, F. ; Cutler, Ann R. ; Walton, Richard A. (1986) Reactivity of the dirhenium(III) carboxylate complexes Re₂(O₂CCH₃)₂X₄(H₂O)₂ (X = Cl or Br) toward monodentate phosphines. A novel disproportionation reaction leading to dirhenium(IV,II) alkoxide complexes of the type (RO)2X2ReReX2(PPh3)2 (X = Cl or Br; R = Me, Et, or Pr) Inorganic Chemistry, 25 (20). pp. 3619-3624. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic00240a018

Related URL: http://dx.doi.org/10.1021/ic00240a018

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Item Type:	Article
Source:	Copyright of this article belongs to American Chemical Society.
ID Code:	6245
Deposited On:	20 Oct 2010 11:24
Last Modified:	27 May 2011 05:28

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Reactivity of the dirhenium(III) carboxylate complexes Re2(O2CCH3)2X4(H2O)2 (X = Cl or Br) toward monodentate phosphines. A novel disproportionation reaction leading to dirhenium(IV,II) alkoxide complexes of the type (RO)2X2ReReX2(PPh3)2 (X = Cl or Br; R = Me, Et, or Pr)

Abstract

Reactivity of the dirhenium(III) carboxylate complexes Re₂(O₂CCH₃)₂X₄(H₂O)₂ (X = Cl or Br) toward monodentate phosphines. A novel disproportionation reaction leading to dirhenium(IV,II) alkoxide complexes of the type (RO)2X2ReReX2(PPh3)2 (X = Cl or Br; R = Me, Et, or Pr)