Chandrasekhar, S. ; Jaya Prakash, S. ; Shyamsunder, T. (2005) Asymmetric synthesis of the pyran antibiotic (−)-centrolobine Tetrahedron Letters, 46 (39). pp. 6651-6653. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.07.162
Abstract
An expedient total synthesis of (−)-centrolobine is achieved involving asymmetric Keck allylation and stereoselective intramolecular oxy-Michael reactions as key steps in 8% overall yield.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Keck Allylation; Intramolecular Oxy-Michael Reaction; (−)-Centrolobine; 2, 6-Disubstituted Tetrahydropyran |
| ID Code: | 62403 |
| Deposited On: | 22 Sep 2011 03:27 |
| Last Modified: | 22 Sep 2011 03:27 |
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