Asymmetric synthesis of the pyran antibiotic (−)-centrolobine

Chandrasekhar, S. ; Jaya Prakash, S. ; Shyamsunder, T. (2005) Asymmetric synthesis of the pyran antibiotic (−)-centrolobine Tetrahedron Letters, 46 (39). pp. 6651-6653. ISSN 0040-4039

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An expedient total synthesis of (−)-centrolobine is achieved involving asymmetric Keck allylation and stereoselective intramolecular oxy-Michael reactions as key steps in 8% overall yield.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Keck Allylation; Intramolecular Oxy-Michael Reaction; (−)-Centrolobine; 2, 6-Disubstituted Tetrahydropyran
ID Code:62403
Deposited On:22 Sep 2011 03:27
Last Modified:22 Sep 2011 03:27

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