Chandrasekhar, S. ; Pavan Kumar Reddy, G. ; Nagesh, Ch. ; Raji Reddy, Ch. (2007) A novel one-pot conversion of amines to homologated esters in poly(ethylene glycol) Tetrahedron Letters, 48 (7). pp. 1269-1271. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.12.035
Abstract
The first deaminative homologation of amines (-CH2NH2) to esters (-CH2CH2COOEt) in one-pot is reported. The reaction proceeds through, formation of an aldehyde from an amine in the presence of Pd/C as catalyst followed by Wittig reaction and catalytic hydrogenation using poly(ethylene glycol) as the solvent in one-pot.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Palladium; One-pot Reaction; Poly(ethylene Glycol); Amines; Esters |
| ID Code: | 62374 |
| Deposited On: | 22 Sep 2011 03:32 |
| Last Modified: | 22 Sep 2011 03:32 |
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