Reductive N-alkylation of aromatic amines and nitro compounds with nitriles using polymethylhydrosiloxane

Raji Reddy, Ch. ; Vijeender, K. ; Bibhuti Bhusan, P. ; Phani Madhavi, P. ; Chandrasekhar, S. (2007) Reductive N-alkylation of aromatic amines and nitro compounds with nitriles using polymethylhydrosiloxane Tetrahedron Letters, 48 (15). pp. 2765-2768. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.02.050

Abstract

The potential utility of polymethylhydrosiloxane (PMHS) as a reducing agent for reductive N-alkylation of aromatic amines and nitro compounds using nitriles as an alkylating agent and Pd(OH)2/C as a catalyst is described. The application of this method for the synthesis of several heterocyclic compounds is also reported.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Alkylation; Amines; Nitro Compounds; Nitriles; Polymethylhydrosiloxane
ID Code:62372
Deposited On:22 Sep 2011 03:32
Last Modified:22 Sep 2011 03:32

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