Towards the synthesis of Palmerolide A: asymmetric synthesis of C1-C14 fragment

Chandrasekhar, S. ; Vijeender, K. ; Chandrashekar, G. ; Raji Reddy, Ch. (2007) Towards the synthesis of Palmerolide A: asymmetric synthesis of C1-C14 fragment Tetrahedron: Asymmetry, 18 (20). pp. 2473-2478. ISSN 0957-4166

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetasy.2007.10.011

Abstract

The synthesis of a C1-C14 fragment of a marine cytotoxic natural product Palmerolide A is described. The key steps involved in this synthesis are deoxygenative rearrangement of an alkynol followed by an asymmetric dihydroxylation of a diene ester and CBS-reduction.

Item Type:Article
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ID Code:62367
Deposited On:22 Sep 2011 03:33
Last Modified:22 Sep 2011 03:33

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