Dileesh, S. ; Gopidas, K. R. (2004) Photoinduced electron transfer in azatriangulenium salts Journal of Photochemistry and Photobiology A: Chemistry, 162 (1). pp. 115-120. ISSN 1010-6030
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S1010-6030(03)00318-6
Abstract
Fluorescence quenching and laser flash photolysis studies of stable azatriangulenium ions 2⊕-4⊕ are reported. The fluorescence quenching rate constants were correlated to Δ G0values. The results suggest that 2⊕ is an excited state electron acceptor and 4⊕ is an excited state electron donor. 3⊕, on the other hand, can act as an acceptor or donor in photoinduced electron transfer (PET) reactions. Laser flash photolysis studies also supported these observations. These cations thus present an interesting case, where replacement of oxygen atoms by N-alkyl groups leads to a gradual shift of photoinduced electron transfer property from an acceptor to that of a donor.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Photoinduced Electron Transfer; Azatriangulenium Salts; Radical Ions; Fluorescence Quenching; Laser Flash Photolysis |
| ID Code: | 62095 |
| Deposited On: | 16 Sep 2011 04:36 |
| Last Modified: | 16 Sep 2011 04:36 |
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