Photoinduced charge transfer processes in ultrasmall semiconductor clusters. Photophysical properties of CdS clusters in nafion membrane

Gopidas, K. R. ; Kamat, Prashant V. (1993) Photoinduced charge transfer processes in ultrasmall semiconductor clusters. Photophysical properties of CdS clusters in nafion membrane Journal of Chemical Sciences, 105 (6). pp. 505-512. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/j_archive/chemsci/105/vol105c...

Related URL: http://dx.doi.org/10.1007/BF03040822

Abstract

The photophysical properties of quantized CdS clusters in a perfluorosulfonate polymer (Nafion) film have been investigated by time-resolved emission spectroscopy. The ultrasmall CdS clusters were prepared by exposing Cd2+-exchanged polymer film to H2S. size-dependent absorption and emission properties were observed during the growth of these clusters. The emission decay is multiexponential with lifetimes ranging from 0·85 to 480 ns.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Semiconductor Clusters; CdS; Size Quantization Effect; Nafion; Emission Lifetimes
ID Code:62071
Deposited On:16 Sep 2011 04:07
Last Modified:16 Sep 2011 04:07

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