The origin of ferromagnetism in the two different phases of LaMn0.5Co0.5O3: evidence from X-ray photoelectron spectroscopic studies

Joseph Joly, V. L. ; Joy, P. A. ; Date, S. K. ; Gopinath, C. S. (2001) The origin of ferromagnetism in the two different phases of LaMn0.5Co0.5O3: evidence from X-ray photoelectron spectroscopic studies Journal of Physics: Condensed Matter, 13 (4). pp. 649-656. ISSN 0953-8984

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Official URL: http://iopscience.iop.org/0953-8984/13/4/311/

Related URL: http://dx.doi.org/10.1088/0953-8984/13/4/311

Abstract

Core-level Mn and Co 2p X-ray photoelectron spectroscopic studies give evidence for different spin states of Mn and Co in the two different phases of the ferromagnetic compound LaMn0.5Co0.5O3. Ferromagnetism in the high-Tc (Tc≈230 K) phase of the compound arises from Mn3+-O-Mn3+ superexchange interactions, whereas in the low-Tc (Tc≈150 K) phase Mn4+-O-Co2+ superexchange interactions are responsible for the ferromagnetism.

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