Investigation of 4f-magnetism in CeNi2P2, EuNi2P2 and YbNi2P2 by susceptibility and NMR studies

Nambudripad, N. ; Sampathkumaran, E. V. ; Vijayaraghavan, R. ; Stang, I. ; Lüders, K. (1986) Investigation of 4f-magnetism in CeNi2P2, EuNi2P2 and YbNi2P2 by susceptibility and NMR studies Solid State Communications, 60 (8). pp. 625-628. ISSN 0038-1098

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0038-1098(86)90255-3

Abstract

The results of 31P NMR Knight shift (KS) and spin-lattice relaxation time (T1) as well as magnetic susceptibility (ξ) measurements in the temperature interval 4.2-300K are reported for the compounds RENi2P2(RE = Ce, EuandYb) in order to understand the nature of the 41 magnetism in these compounds. The KS results conclusively establish that all these compounds exhibit non-magnetic ground states. There is a low-temperature upturn in ξ for CeNi2P2 and YbNi2P2 presumably due to magnetic impurities. The estimated spin fluctuation temperatures (Tsf) for EuNi2P2 above 50K agree qualitatively with those obtained earlier from Mössbauer and ξ data employing ionic interconfigurational fluctuation model, but seem to disagree at low temperatures. Implications of this result are discussed.

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