Fusicoccin. Part III. The structure of Fusicoccin H

Barrow, Kevin D. ; Barton, Derek H. R. ; Chain, Ernst ; Ulrich, F. W. (1973) Fusicoccin. Part III. The structure of Fusicoccin H Journal of the Chemical Society, Perkin Transactions 1 . pp. 1590-1599. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1973...

Related URL: http://dx.doi.org/10.1039/P19730001590


The structure (IIa) of fusicoccin H, a minor phytotoxic glycoside produced by Fusicoccum amydali, has been determined by degradative studies and by chemical correlation with the known fusicoccin series. Feeding experiments have shown that fusicoccin H can act as a precursor of fusicoccin. This strongly suggests that fusicoccin is a diterpenoid and not a degraded sesterterpenoid.

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