Formation of aryl isocyanates by deoxygenation of nitrosocarbonylarenes

Corrie, John E. T. ; Kirby, Gordon W. ; Sharma , Ram P. (1975) Formation of aryl isocyanates by deoxygenation of nitrosocarbonylarenes Journal of the Chemical Society, Chemical Communications (22). pp. 915-916. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1975...

Related URL: http://dx.doi.org/10.1039/C39750000915

Abstract

The adducts of nitrosocarbonylarenes and 9,10-dimethylanthracene decompose in the presence of triphenylphosphine to give aryl isocyanates in high yield; kinetic evidence supporting the involvement of free nitrosocarbonylarenes in this process is presented.

Item Type:Article
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ID Code:61434
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