Reaction of nitro-alkenes with iodotrimethylsilane: a new method for the conversion of vinyl nitrosteroids to ketosteroids

Singhal, Gireesh M. ; Das, Nalin B. ; Sharma, Ram P. (1989) Reaction of nitro-alkenes with iodotrimethylsilane: a new method for the conversion of vinyl nitrosteroids to ketosteroids Journal of the Chemical Society, Chemical Communications (19). pp. 1470-1471. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1989...

Related URL: http://dx.doi.org/10.1039/C39890001470

Abstract

Iodotrimethylsilane generated in situ from chlorotrimethylsilane and sodium iodide effects the reduction of nitro-alkenes (1a-e) and (5) at -5 to 0°C to furnish the ketones (2a-e) and (6) respectively as the major products.

Item Type:Article
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