[3 + 2]-Cycloaddition of nonstabilized azomethine ylides. 10. an efficient strategy for the construction of x-azatricyclo[m.n.0.0a,b]alkanes by intramolecular cycloaddition of cyclic azomethine ylide

Pandey, Ganesh ; Sahoo, Akhila K. ; Bagul, Trusar D. (2000) [3 + 2]-Cycloaddition of nonstabilized azomethine ylides. 10. an efficient strategy for the construction of x-azatricyclo[m.n.0.0a,b]alkanes by intramolecular cycloaddition of cyclic azomethine ylide Organic Letters, 2 (15). pp. 2299-2301. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol006070s

Related URL: http://dx.doi.org/10.1021/ol006070s

Abstract

Various new structural entities related to x-azatricyclo[m.n.0.0a,b]alkanes are constructed by the intramolecular [3 + 2] dipolar cycloaddition of nonstabilized cyclic azomethine ylides. The ylide is generated by the sequential double desilylation of N-alkyl α ,α '-bis(trimethylsilyl)cyclic amines using Ag(I)F as a one-electron oxidant.

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