Pandey, Ganesh ; Devi Reddy, G. ; Kumaraswamy, G. (1994) Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: mechanistic and synthetic perspectives Tetrahedron, 50 (27). pp. 8185-8194. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)85300-X
Abstract
Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α -silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 60982 |
| Deposited On: | 13 Sep 2011 11:24 |
| Last Modified: | 13 Sep 2011 11:24 |
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