Datta, Ayan ; Pati, Swapan K. (2005) New examples of metalloaromatic Al-clusters: (Al4M4)Fe(CO)3 (M = Li, Na and K) and (Al4M4)2Ni: rationalization for possible synthesis Chemical Communications (40). pp. 5032-5034. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2005...
Related URL: http://dx.doi.org/10.1039/B508123H
Abstract
Ab initio calculations reveal that all-metal antiaromatic molecules like Al4M4 (M = Li, Na and K) can be stabilized in half sandwich (Al4M4)Fe(CO)3 and full sandwich (Al4M4)2Ni complexes. The formation of the full sandwich complex [(Al4M4)2Ni] from its organometallic precursor depends on the stability of the organic-inorganic hybrid (C4H4)Ni(Al4Li4).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 60834 |
| Deposited On: | 12 Sep 2011 07:07 |
| Last Modified: | 12 Sep 2011 07:07 |
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