Corundum, diamond, and ptS metal-organic frameworks with a difference: self-assembly of a unique pair of 3-connecting D2d-symmetric 3,3',5,5'-tetrakis(4-pyridyl)bimesityl

Natarajan, Ramalingam ; Savitha, Govardhan ; Dominiak, Paulina ; Wozniak, Krzysztof ; Narasimha Moorthy, J. (2005) Corundum, diamond, and ptS metal-organic frameworks with a difference: self-assembly of a unique pair of 3-connecting D2d-symmetric 3,3',5,5'-tetrakis(4-pyridyl)bimesityl Angewandte Chemie International Edition, 44 (14). pp. 2115-2119. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200461625

Abstract

A ligand with a twist: The coordination of distorted-tetrahedral D2d-symmetric tetrapyridylbimesityl (tpb) with Oh, Td, and D4h metal centers leads to metal-organic frameworks with unprecedented topologies related to those of corundum, diamond, and PtS, respectively (see picture).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Coordination Modes; Crystal Engineering; N Ligands; Self-assembly; Supramolecular Chemistry
ID Code:60720
Deposited On:10 Sep 2011 11:39
Last Modified:10 Sep 2011 11:39

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