Preparation of 1,3-dienes, its application to the synthesis of (Z,E)-9,11-tetradecadienyl acetate and (E,E)-10,12-hexa-decadienal: sex pheromones of cotton pests

Yadav, J. S. ; Deshpande, Prasad K. ; Rajarathnam Reddy, E. (1989) Preparation of 1,3-dienes, its application to the synthesis of (Z,E)-9,11-tetradecadienyl acetate and (E,E)-10,12-hexa-decadienal: sex pheromones of cotton pests Synthetic Communications, 19 (1-2). pp. 125-134. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397918908050960

Abstract

E-2-Penten-4-yn-1-ol (3) has been utilized as a source for 1,3-diene systems by employing lithium amide induced alkylation, and curpous iodide catalysed Grignard coupling reaction as key steps. Its application for the synthesis of (Z,E)-9,11-tetradecadienyl acetate and (E,E)-10,12-hexadecadienal is described.

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