Bi(OTf)3-catalyzed allylation of epoxides: a facile synthesis of homoallylic alcohols

Yadav, J. S. ; Reddy, B. V. S. ; Satheesh, G. (2003) Bi(OTf)3-catalyzed allylation of epoxides: a facile synthesis of homoallylic alcohols Tetrahedron Letters, 44 (34). pp. 6501-6504. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01559-4

Abstract

Epoxides react smoothly with tetraallyltin in the presence of 2 mol% of Bi(OTf)3 under mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high regioselectivity while aryl aziridines produce exclusively allyl amines in good yields under similar conditions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Bismuth Triflate; Allylation; Oxiranes; Homoallylic Alcohols
ID Code:60417
Deposited On:09 Sep 2011 03:52
Last Modified:09 Sep 2011 03:52

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