Miller, Joel S. ; Dixon, David A. ; Scott. McLean, R. ; Groski, David M. ; Flippen, Richard B. ; Manriquez, Juan M. ; Yee, Gordon T. ; Narayan, K. S. ; Epstein, Arthur J. (1991) Decamethylmanganocenium tetracyanoethenide, [Mn(C5Me5)2]⊙⊙⊕[TCNE]⊙⊖-a molecular ferromagnet with an 8.8 K Tc Advanced Materials, 3 (6). pp. 309-311. ISSN 1521-4095
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adma.19...
Related URL: http://dx.doi.org/10.1002/adma.19910030609
Abstract
Communication Triplet electron- transfer salts are predicted to exhibit bulk ferromagnetic behavior at higher temperatures than their singlet analogues. To test this expected trend, the title compound, which is isostructural with [FeCp2]⊙⊕ [TCNE]⊙⊖ (Cp* = pentamethylcyloopentadienide; TCNE = tetracyanoethylene) which exhibits a Curie temperature, Tc, of 4.8 K has been synthesized. The synthesis and magnetic characterization of the new compound, which is found to have a Tc of 8.8 K, are reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 60078 |
| Deposited On: | 08 Sep 2011 10:03 |
| Last Modified: | 08 Sep 2011 10:03 |
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