Shukla, Atindra D. ; Dave, Paresh C. ; Suresh, Eringathodi ; Das, Amitava ; Dastidar, Parthasarathi (2000) Multicomponent Zn-tetraphenylporphyrins: syntheses, characterization and their self assembly in the solid state Journal of the Chemical Society Dalton Transactions, 2000 (23). pp. 4459-4463. ISSN 1472-7773
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/2000...
Related URL: http://dx.doi.org/10.1039/B004211K
Abstract
Two multicomponent Zn-tetraphenylporphyrin (ZnTPP) based building blocks have been synthesized for designing microporous crystalline solids. Reactions of ZnTPP with 4,4'-bipyridine (4,4'-bpy) in two different molar ratios gave two coordination complexes namely [(ZnTPP)3{μ-4,4'-bpy}2] I and [(ZnTPP)2{μ-4,4'-bpy}] II. Complexes I and II were characterized by spectroscopic and analytical methods. Inclusion complexes of I with toluene, II with toluene, and also with nitrobenzene have been prepared and are characterized by 1H NMR and single crystal X-ray diffraction techniques. Supramolecular structural systematics of TPP-based materials are conserved in these crystals.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 59983 |
| Deposited On: | 08 Sep 2011 04:36 |
| Last Modified: | 06 Jan 2012 08:49 |
Repository Staff Only: item control page
