Synthesis, characterization and physicochemical studies of weakly interacting redox-responsive binuclear complexes incorporating ethylenediaminetetraacetatoruthanate(III)

Das, Amitava ; Bajaj, H. C. ; Chatterjee, Debabrata (1995) Synthesis, characterization and physicochemical studies of weakly interacting redox-responsive binuclear complexes incorporating ethylenediaminetetraacetatoruthanate(III) Polyhedron, 14 (23-24). pp. 3585-3589. ISSN 0277-5387

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0277-5387(95)00171-N

Abstract

Novel binuclear complexes of the type [{Ru(edtaH)}2L] [edta- = ethylenediaminetetraacetate, L = pyrazine, 4,4'-bipyridyl, 3,3'-dimethyl-4,4'-bipyridyl, trans-1,2-bis(4-pyridyl)ethylene)] have been synthesized and characterized by physicochemical methods. All the complexes showed weak metal-metal interaction, depending on the nature of the bridging ligand, L. The electrochemical and magnetic susceptibility measurements are consistent with weak interactions between the ruthenium centres.

Item Type:Article
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Deposited On:07 Sep 2011 14:17
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