Synthesis of (+)-amberketal and its analog from L-abietic acid

Yadav, J. S. ; Baishya, Gakul ; Dash, Uttam (2007) Synthesis of (+)-amberketal and its analog from L-abietic acid Tetrahedron, 63 (39). pp. 9896-9902. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2007.06.063

Abstract

(+)-Amberketal (1) and its analog (2) have been synthesized from commercially available L-abietic acid (3) by a selective reduction of an unsaturated aldehyde in the presence of a ketone and simultaneous reduction of an iodide using an aqueous suspension of Raney Ni as the key step.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:L-abietic Acid; Regioselective Dihydroxylation; δε-epoxyketone Cyclization; (+)-amberketal
ID Code:59660
Deposited On:07 Sep 2011 05:46
Last Modified:07 Sep 2011 05:46

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