Gallium(III) halide promoted synthesis of 1,3,5-triaryl- 1,5-dihalo-1,4-pentadienes

Yadav, J. S. ; Reddy, B. V. S. ; Eeshwaraiah, B. ; Gupta, Manoj Kumar ; Biswas, Swapan Kumar (2005) Gallium(III) halide promoted synthesis of 1,3,5-triaryl- 1,5-dihalo-1,4-pentadienes Tetrahedron Letters, 46 (7). pp. 1161-1163. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.12.080

Abstract

Aryl substituted alkynes undergo smooth coupling with aldehydes in the presence of gallium(III) halides under extremely mild conditions to afford the corresponding 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes in good yields with E,Z-selectivity. Similarly 1,3,5-triaryl-1,5-dichloro-1,4-pentadienes are also obtained with niobium(V) chloride.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Gallium(III) Compounds; Aldehydes; Alkynes; 1,4-pentadienes
ID Code:59624
Deposited On:07 Sep 2011 05:40
Last Modified:07 Sep 2011 05:40

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