Green approach for the conversion of olefins into vic-halohydrins using N-halosuccinimides in ionic liquids

Yadav, J. S. ; Reddy, B. V. S. ; Baishya, Gakul ; Harshavardhan, S. J. ; Janardhana Chary, Ch. ; Gupta, Manoj Kumar (2005) Green approach for the conversion of olefins into vic-halohydrins using N-halosuccinimides in ionic liquids Tetrahedron Letters, 46 (20). pp. 3569-3572. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.03.108

Abstract

Alkenes undergo smooth bromo- and iodohydroxylation with N-bromo- and N-iodosuccinimides/water, respectively, using the air and moisture stable ionic liquid [bmim]BF4 as a novel recyclable reaction medium in high to quantitative yields. N-Halosuccinimides show enhanced reactivity in ionic liquids thereby reducing the reaction times and improving the yields considerably.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ionic Liquids (ILs); Alkenes; Halohydroxylation; Halohydrins
ID Code:59597
Deposited On:07 Sep 2011 05:41
Last Modified:07 Sep 2011 05:41

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