Bi(OTf)3/[bmim]BF4 as novel and reusable catalytic system for the synthesis of furan, pyrrole and thiophene derivatives

Yadav, J. S. ; Reddy, B. V. S. ; Eeshwaraiah, B. ; Gupta, Manoj Kumar (2004) Bi(OTf)3/[bmim]BF4 as novel and reusable catalytic system for the synthesis of furan, pyrrole and thiophene derivatives Tetrahedron Letters, 45 (30). pp. 5873-5876. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.05.152

Abstract

Bi(OTf)3 immobilized in 1-butyl-3-methylimidazolium tetrafluoroborate [bmim]BF4 has been utilized for the first time as a novel and reusable catalytic system for the synthesis of heteroaromatics such as furan, pyrrole and thiophene derivatives from 1,4-diketones. This new procedure offers significant improvements in reaction rates and yields. The recovered ionic liquid containing bismuth triflate can be reused for subsequent runs with only a gradual decrease in activity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ionic Liquids (ILs); Bismuth Catalysis; 1,4-diketones; Heteroaromatics
ID Code:59587
Deposited On:07 Sep 2011 05:39
Last Modified:07 Sep 2011 05:39

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