Yadav, J. S. ; Praveen Kumar, T. K. ; Maniyan, P. P. (1993) Stereoconvergent synthesis of C-9 to C-16 fragment of trienomycin based on the regioselective opening of γ-δ-poxy acrylates with Trimethylaluminium Tetrahedron Letters, 34 (18). pp. 2969-2972. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)60495-1
Abstract
The C-9 to C-16 fragment, a key intermediate for the synthesis of a 21 membered ansamycin antibiotic, Trienomycin has been synthesized, involving Sharpless asymmetric epoxidation and the key stereoselective methylation of γ-δ-epoxy acrylates by Trimethylaluminium.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59579 |
| Deposited On: | 07 Sep 2011 05:24 |
| Last Modified: | 07 Sep 2011 05:24 |
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