Mohapatra, Debendra K. ; Prabhakar Reddy, D. ; Dash, Uttam ; Yadav, J. S. (2011) Total synthesis of Z-isomer of phomolide B Tetrahedron Letters, 52 (1). pp. 151-154. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.11.003
Abstract
We have achieved the synthesis of Z-isomer of phomolide B during our investigation toward the effect of protecting group on the outcome of ring-closing metathesis reaction. The other key reactions involved are cis-selective partial hydrogenation, Sharpless asymmetric epoxidation, Yamaguchi esterification, and following 12 longest linear sequence with 18.5% overall yield starting from a known intermediate 20.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Phomolide B; Decanolides; Sharpless Asymmetric Epoxidation; Yamaguchi Esterification; Ring-closing Metathesis |
| ID Code: | 59529 |
| Deposited On: | 07 Sep 2011 05:58 |
| Last Modified: | 07 Sep 2011 05:58 |
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