Bhuyan, Jagannath ; Sarkar, Sabyasachi (2010) Oxidative degradation of zinc porphyrin in comparison with its iron analogue Chemistry - A European Journal, 16 (35). pp. 10649-10652. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201001073
Abstract
Zinc hydroxyisoporphyrin (2), under sunlight and argon, is reduced back to zinc meso-tetraphenylporphyrin (1), but stays stable in oxygen in the absence of light. This behavior is in contrast to its iron analogue and stresses the redox role of iron in heme degradation. Compound 2 also responds to chlorophyll-type degradation (3) under sunlight and oxygen.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Density Functional Calculations; Hydroxylation; Porphyrinoids; X-ray Crystallography; Zinc |
| ID Code: | 59335 |
| Deposited On: | 06 Sep 2011 06:13 |
| Last Modified: | 06 Sep 2011 06:13 |
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