NO2-mediated meso-hydroxylation of iron(III) porphyrin

Abhilash, G. J. ; Bhuyan, Jagannath ; Singh, Pinky ; Maji, Suman ; Pal, Kuntal ; Sarkar, Sabyasachi (2009) NO2-mediated meso-hydroxylation of iron(III) porphyrin Inorganic Chemistry, 48 (5). pp. 1790-1792. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic800864w

Related URL: http://dx.doi.org/10.1021/ic800864w

Abstract

· NO2 generated from · NO and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.

Item Type:Article
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Deposited On:07 Sep 2011 06:26
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